Carbon dating theory
Willard Libby (1908–1980), a professor of chemistry at the University of Chicago, began the research that led him to radiocarbon dating in 1945.
He was inspired by physicist Serge Korff (1906–1989) of New York University, who in 1939 discovered that neutrons were produced during the bombardment of the atmosphere by cosmic rays.
Living organisms from today would have the same amount of carbon-14 as the atmosphere, whereas extremely ancient sources that were once alive, such as coal beds or petroleum, would have none left.
For organic objects of intermediate ages—between a few centuries and several millennia—an age could be estimated by measuring the amount of carbon-14 present in the sample and comparing this against the known half-life of carbon-14.
Using this sample and an ordinary Geiger counter, Libby and Anderson established the existence of naturally occurring carbon-14, matching the concentration predicted by Korff. Fortunately, Libby’s group developed an alternative. They surrounded the sample chamber with a system of Geiger counters that were calibrated to detect and eliminate the background radiation that exists throughout the environment.
The assembly was called an “anti-coincidence counter.” When it was combined with a thick shield that further reduced background radiation and a novel method for reducing samples to pure carbon for testing, the system proved to be suitably sensitive.
Based on Korff’s estimation that just two neutrons were produced per second per square centimeter of earth’s surface, each forming a carbon-14 atom, Libby calculated a ratio of just one carbon-14 atom per every 10 carbon atoms on earth.
Further research by Libby and others established its half-life as 5,568 years (later revised to 5,730 ± 40 years), providing another essential factor in Libby’s concept.
But no one had yet detected carbon-14 in nature— at this point, Korff and Libby’s predictions about radiocarbon were entirely theoretical.
In order to prove his concept of radiocarbon dating, Libby needed to confirm the existence of natural carbon-14, a major challenge given the tools then available.
They also sampled artifacts from museums such as a piece of timber from Egyptian pharaoh Senusret III’s funerary boat, an object whose age was known by the record of its owner’s death.
In 1949, Libby and Arnold published their findings in the journal Science, introducing the “Curve of Knowns.” This graph compared the known age of artifacts with the estimated age as determined by the radiocarbon dating method.